Novel organosilicon monomer for preparing transparent matrices doped with lanthanide complexes

…, VI Faerman, AY Dolgonosova, MA Baten'kin…

Index: Ladilina, E. Yu.; Lyubova; Semenov; Kuznetsova; Kirillov; Faerman; Dolgonosova; Baten'kin; Lopatin Russian Chemical Bulletin, 2010 , vol. 59, # 3 p. 590 - 597

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Citation Number: 4

Abstract

Abstract Perfluoroadipic bis (trialkoxysilylpropyl) amide was synthesized as a mixture of five compounds with the general formula (EtO) n (MeO) 3-n Si (CH 2) 3 NHC (O)(CF 2) 4 C (O) NH (CH 2) 3-Si (OMe) n (OEt) 3-n (1, n= 1, 2). Hydrolysis of this product by a specified amount of water (1: 4) gave oligomers EtO [(HO)(EtO) Si (CH 2) 3 NH (O) C (CF 2) 4 C (O) NH (CH 2) 3 Si (OEt) 2 O] n H (n= 7–9). From oligomer solutions, transparent glassy ...