The Synthesis of 2-Fluoro-DL-tyrosine and 2-Fluoro-4-methoxy-DL-phenylalanine

EL Bennett, C Niemann

Index: Bennett; Niemann Journal of the American Chemical Society, 1950 , vol. 72, p. 1806

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Citation Number: 9

Abstract

92% series of reactions: 2-amino-4-nitrotoluene-+-2-methyl-5-nitrobenzenediazonium fluoroborate 58% 93%+ 2-fluoro-4-nitrotoluene+ 2-fluoro-4-aminotoluene-+-2-fluoro-4- hydroxytoluene+ 2-fluoro-4-methoxytoluene-+ 2-fluoro-4-methoxybenzoic acid+ 2-fluoro-4- methoxybenzoyl chloride+ 2-fluoro-4-methoxybenzyl chloride+ diethyl a-acetamido-a-(2- fluoro-4-methoxybenzyl)-malonate+ N-acetyl-2-fluoro-4-methoxy-DL-phenylalanine. The ...