The Journal of Organic Chemistry

Migrations in oxidations of mesidine

SL Goldstein, E McNelis

Index: Goldstein, Stephen L.; McNelis, Edward Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1613 - 1620

Full Text: HTML

Citation Number: 14

Abstract

(1) Goldstein, SL; McNelis, EJ Org. Chem. 1973, 38, 183. compound 2 is the principal product in basic systems; anil 3 [2, 6-dimethyl-p-benzoquinone 4-(2, 4, 6-trimethylanil)] is the principal product in acidic systems with or without methanol; anil 4 [2, 6-dimethyl-3- (methoxymethyl)-p-benzoquinone 4-(2, 4, 6-trimethylanil)] is a significant product in acidic systems containing methanol. The mechanism of removal or shifts of the methyl groups ...

 Related Synthetic Route
(3,5-Dimethyl-4-nitrophenyl)methanol Structure

18515-22-5

(3,5-Dimethyl-4...

~%

4-(methoxymethyl)-2,6-dimethylaniline,hydrochloride Structure

89210-29-7

4-(methoxymethy...

4-Bromomethyl-2,6-dimethylnitrobenzene Structure

40113-65-3

4-Bromomethyl-2...

~%

4-(methoxymethyl)-2,6-dimethylaniline,hydrochloride Structure

89210-29-7

4-(methoxymethy...

2-nitromesitylene Structure

603-71-4

2-nitromesitylene

~%

4-(methoxymethyl)-2,6-dimethylaniline,hydrochloride Structure

89210-29-7

4-(methoxymethy...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~%

4-(methoxymethyl)-2,6-dimethylaniline,hydrochloride Structure

89210-29-7

4-(methoxymethy...

4-(methoxymethyl)-2,6-dimethylnitrobenzene Structure

40113-64-2

4-(methoxymethy...

~%

4-(methoxymethyl)-2,6-dimethylaniline,hydrochloride Structure

89210-29-7

4-(methoxymethy...

2,6-dimethyl-4-(2,4,6-trimethylphenyl)iminocyclohexa-2,5-dien-1-one Structure

14033-86-4

2,6-dimethyl-4-...

~75%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

2,4,6-Trimethylaniline Structure

88-05-1

2,4,6-Trimethyl...

~%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

(3,5-Dimethyl-4-nitrophenyl)methanol Structure

18515-22-5

(3,5-Dimethyl-4...

~%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

2-nitromesitylene Structure

603-71-4

2-nitromesitylene

~%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

3,5-dimethyl-4-nitrobenzaldehyde Structure

18515-18-9

3,5-dimethyl-4-...

~%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

~%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

N/A Structure

910614-10-7

N/A

~%

2,6-dimethyl-4-(2,4,6-trimethylanilino)phenol Structure

89231-62-9

2,6-dimethyl-4-...

2,4,6-Trimethylaniline Structure

88-05-1

2,4,6-Trimethyl...

~2%

2,6-dimethyl-4-(2,4,6-trimethylphenyl)iminocyclohexa-2,5-dien-1-one Structure

14033-86-4

2,6-dimethyl-4-...

2,6-dimethyl-3-(methoxymethyl)-p-benzoquinone 4-(2,4,6-trimethylanil) Structure

40113-57-3

2,6-dimethyl-3-...

(E)-Dimesityldiazene Structure

5692-66-0

(E)-Dimesityldiazene

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

~0%

2,6-dimethyl-4-(2,4,6-trimethylphenyl)iminocyclohexa-2,5-dien-1-one Structure

14033-86-4

2,6-dimethyl-4-...

(E)-Dimesityldiazene Structure

5692-66-0

(E)-Dimesityldiazene

N/A Structure

910614-10-7

N/A

~%

(E)-Dimesityldiazene Structure

5692-66-0

(E)-Dimesityldiazene

4-(4-ethyl-2,6-dimethylphenoxy)-2-phenylquinazoline Structure

89210-32-2

4-(4-ethyl-2,6-...

~91%

3-(4-ethyl-2,6-dimethylphenyl)-2-phenylquinazolin-4-one Structure

89210-33-3

3-(4-ethyl-2,6-...

3,5-dimethyl-4-nitrobenzoyl chloride Structure

3558-73-4

3,5-dimethyl-4-...

benzene Structure

71-43-2

benzene

~75%

(3,5-dimethyl-4-nitrophenyl)-phenylmethanone Structure

89210-36-6

(3,5-dimethyl-4...

2-nitromesitylene Structure

603-71-4

2-nitromesitylene

~%

(3,5-dimethyl-4-nitrophenyl)-phenylmethanone Structure

89210-36-6

(3,5-dimethyl-4...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~%

(3,5-dimethyl-4-nitrophenyl)-phenylmethanone Structure

89210-36-6

(3,5-dimethyl-4...

3,5-dimethyl-4-nitrobenzhydrol Structure

89210-37-7

3,5-dimethyl-4-...

~80%

4-benzyl-2,6-dimethylaniline,hydrochloride Structure

89210-38-8

4-benzyl-2,6-di...

2-nitromesitylene Structure

603-71-4

2-nitromesitylene

~%

4-benzyl-2,6-dimethylaniline,hydrochloride Structure

89210-38-8

4-benzyl-2,6-di...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~%

4-benzyl-2,6-dimethylaniline,hydrochloride Structure

89210-38-8

4-benzyl-2,6-di...

3,5-dimethyl-4-nitrobenzoyl chloride Structure

3558-73-4

3,5-dimethyl-4-...

~%

4-benzyl-2,6-dimethylaniline,hydrochloride Structure

89210-38-8

4-benzyl-2,6-di...

(3,5-dimethyl-4-nitrophenyl)-phenylmethanone Structure

89210-36-6

(3,5-dimethyl-4...

~%

4-benzyl-2,6-dimethylaniline,hydrochloride Structure

89210-38-8

4-benzyl-2,6-di...

2,4,6-Trimethylphenol Structure

527-60-6

2,4,6-Trimethyl...

~56%

4,4'-Methylenebis(2,6-dimethylphenol) Structure

5384-21-4

4,4'-Methyleneb...

(3,5-Dimethyl-4-nitrophenyl)methanol Structure

18515-22-5

(3,5-Dimethyl-4...

~92%

3,5-dimethyl-4-nitrobenzaldehyde Structure

18515-18-9

3,5-dimethyl-4-...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~%

3,5-dimethyl-4-nitrobenzaldehyde Structure

18515-18-9

3,5-dimethyl-4-...

(3,5-Dimethyl-4-nitrophenyl)methanol Structure

18515-22-5

(3,5-Dimethyl-4...

~62%

(4-amino-3,5-dimethylphenyl)methanol Structure

89210-26-4

(4-amino-3,5-di...

2-nitromesitylene Structure

603-71-4

2-nitromesitylene

~%

(4-amino-3,5-dimethylphenyl)methanol Structure

89210-26-4

(4-amino-3,5-di...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~%

(4-amino-3,5-dimethylphenyl)methanol Structure

89210-26-4

(4-amino-3,5-di...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~82%

3,5-dimethyl-4-nitrobenzoyl chloride Structure

3558-73-4

3,5-dimethyl-4-...

2-nitromesitylene Structure

603-71-4

2-nitromesitylene

~%

3,5-dimethyl-4-nitrobenzoyl chloride Structure

3558-73-4

3,5-dimethyl-4-...

N/A Structure

910614-10-7

N/A

~%

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

(3,5-Dimethyl-4-nitrophenyl)methanol Structure

18515-22-5

(3,5-Dimethyl-4...

~%

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

2-nitromesitylene Structure

603-71-4

2-nitromesitylene

~%

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

3,5-DIMETHYL-4-NITROBENZOIC ACID Structure

3095-38-3

3,5-DIMETHYL-4-...

~%

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

3,5-dimethyl-4-nitrobenzaldehyde Structure

18515-18-9

3,5-dimethyl-4-...

~%

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

2,4,6-Trimethylaniline Structure

88-05-1

2,4,6-Trimethyl...

~%

N-[(4-amino-3,5-dimethylphenyl)methyl]-2,4,6-trimethylaniline Structure

89210-27-5

N-[(4-amino-3,5...

2,6-xylyl acetate Structure

876-98-2

2,6-xylyl acetate

~97%

3',5'-Dimethyl-4'-hydroxyacetophenone Structure

5325-04-2

3',5'-Dimethyl-...


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