Molecular addition compounds. 17. Borane and chloroborane adducts with organic sulfides for hydroboration

M Zaidlewicz, JVB Kanth, HC Brown

Index: Zaidlewicz, Marek; Kanth, Josyula V. B.; Brown, Herbert C. Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6697 - 6702

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Citation Number: 20

Abstract

The following sulfides have been examined as borane carriers in comparison with dimethyl sulfide and 1, 4-oxathiane: tert-butyl methyl sulfide, isoamyl methyl sulfide, ethyl isoamyl sulfide, tert-butyl isoamyl sulfide, diisoamyl sulfide, tetrahydrothiophene, tetrahydro- thiopyran, thioanisole, 3-ethylthiotetrahydrofuran, bis (3-tetrahydrofuryl) sulfide, and bis (2- methoxyethyl) sulfide. Their complexing ability toward borane increases in the following ...