Pyrolysis of trichlorosilane in the presence of chloroform

…, ES Abramova, NV Alekseev, EA Chernyshev

Index: Krasnova; Abramova; Alekseev; Chernyshev Russian Chemical Bulletin, 1999 , vol. 48, # 10 p. 1960 - 1963

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Citation Number: 4

Abstract

Abstract The pyrolysis of trichlorosilane in the presence of different amounts of chloroform and the copyrolysis of HSiCl 3 with buta-1, 3-diene in the presence of 1 mol.% chloroform were studied. The enthalpies of formation of products resulting from the pyrolysis of HSiCl 3 in the presence of chloroform were calculated by the quantum chemical method. Based on the thermochemical data as well as data from GLC and mass spectrometry, it was ...