Tetrahedron

Basic media behavior of N-[2-(1-hydroxy-2-Y-ethyl) phenyl] ethyl carbamates (Y= SMe, SOMe, SO 2 Me, H, Br, CN)

JLG Ruano, C Pedregal, JH Rodriguez

Index: Ruano, Jose Luis Garcia; Pedregal, Concepcion; Rodriguez, Jesus H. Tetrahedron, 1989 ,  vol. 45,  # 1  p. 203 - 214

Full Text: HTML

Citation Number: 10

Abstract

From the results obtained in the hydrolysis reaction of the carbamate group of some thioderivatives compounds whose common structure is (2→ tOOCNH-C6H4)-CHOH-CH2Y a mechanism is suggested to explain the products, as well as the relationship between the relative configuration of diastereoisomeric sulfoxides (Y= SOMe) with the reaction rate and with the stereochemical outcome. Other interesting and unexpected products are yielded ...