Corticosteroids that have an oxygen functionality at C-11 are important regulatory hormones. 2 Because of this physiological and also clinical importance, much effort has been devoted to solving the problems presented by this class of steroid^,^ especially developing efficient methods for introducing a hydr~ xyacetyl~ and an oxygen substituent5 at'2-17 and C-11 positions, respectively; such functionalities are important for steroidal physiological activity ...