Inorganic Chemistry

Cluster syntheses. 13. Chemistry of sulfido ruthenium carbonyl clusters. Synthesis and characterization of the new unsaturated ruthenium carbonyl …

RD Adams, JE Babin, M Tasi

Index: Adams, Richard D.; Babin, James E.; Tasi, Miklos Inorganic Chemistry, 1986 ,  vol. 25, p. 4514 - 4519            

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Citation Number: 88

Abstract

The compound RU,(CO)~(~~-CO)(~~-S)(1) has been prepared by three methods: pyrolysis and photolysis of RU,(CO)~~(~-SPh)(pH), in 89% and 80% yields, respectively, and the reaction of RU~(CO)~, and ethylene sulfide in 67% yield. The compound RU~(CO)~(~~- S),(3) was prepared in 94% yield from the reaction of RU,(CO)~~ with an excess of ethylene sulfide. Compound 3 was also obtained from the reaction of 1 with ethylene sulfide in 97% ...