The Journal of Organic Chemistry

A novel 3 (2H)-furanone-2 (5H)-furanone rearrangement

RA Mack, V St. Georgiev

Index: Mack, Robert A.; Georgiev, Vassil St. Journal of Organic Chemistry, 1987 ,  vol. 52,  # 3  p. 477 - 478

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Citation Number: 4

Abstract

(CH3)3C 2.10 2.2 15 0.5 81 2.2 13 0.5 64e ... CHB(CH2)d 2.04 2.2 10 0.5 7 9 ... "Based on volume of HzO in pL. bReaction mixtures were heated to reflux and maintained under reflux for the specified pe- riods of time. CThe products separated from the solvent when the reaction mixtures were kept at room temperatues (R = t-Bu, n- C5HI1) or in a refrigerator freezer (R = Me, i-Pr). dBased on un- recrystallized products and rounded off to nearest percent: R (mp, uncorrected); ...