Journal of the American Chemical Society

Oxygen Alkylation of Negatively Substituted Esters1

CO Parker

Index: Parker Journal of the American Chemical Society, 1956 , vol. 78, p. 4944

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Citation Number: 13

Abstract

Discussion Four possible reaction sequences which may occur on treatment of p-bromoethyl esters with base and involving bromide ion displacement may be outlined as have never been isolated previously as the result of nucleophilic displacement by the ester enolate ion, participation of the ester carbonyl oxygen atom in reactions of this sort is of course well known. 5 However, what appears to be involved in the present situation is competition ...