Reaction of 3, 3-Dichloro-2-dichloroacetylaminoacrylonitrile with Amines

SG Pil'o, VS Brovarets, EA Romanenko…

Index: Pil'o; Brovarets; Romanenko; Drach Russian Journal of General Chemistry, 2002 , vol. 72, # 11 p. 1724 - 1729

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Abstract

Abstract Polychlorinated enamidonitrile Cl 2 CÍC (CN) NHCOCHCl 2 readily reacts with primary aromatic amines, dialkylamines, piperidine, and morpholine. The reaction is accompanied by complete elimination of chlorine atoms as chloride ions with formation of 4- cyanooxazoles having the corresponding amine residue in position 5 of the ring and a CHÍN or diaminomethyl moiety in position 2. The structure of 5-arylamino (dialkylamino)-4-cyano ...