Tetrahedron

Preparation and reactivity studies of 1, 2-bis-triisopropylsilanylsulfanyl-alkenes

Y Gareau, M Tremblay, D Gauvreau, H Juteau

Index: Gareau, Yves; Tremblay, Melanie; Gauvreau, Danny; Juteau, Helene Tetrahedron, 2001 , vol. 57, # 27 p. 5739 - 5750

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Citation Number: 24

Abstract

The cross-coupling reaction of bis-triisopropylsilyl disulfide 1 on alkynes yielded 1, 2-bis- triisopropylsilanylsulfanyl-alkenes 2, a new chemical class. A series of tri and tetrasubstituted olefins 2 were prepared and their behavior toward electrophiles was ...