Amination of. pi.-allylpalladium chloride complexes. A mechanistic study

…, G Aakermark, LS Hegedus, K Zetterberg

Index: Akermark, Bjorn; Akermark, Gunilla; Hegedus, Louis S.; Zetterberg, Krister Journal of the American Chemical Society, 1981 , vol. 103, # 11 p. 3037 - 3040

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Citation Number: 44

Abstract

Abstract: Conductivity measurements indicate that the reaction of a-allylpalladium chloride complexes with excess phosphine in THF does not generate cationic a-allylpalladium complexes. Rather, dynamic u-allylpalladium complexes are formed. The reaction of neutral a-allylpalladium chloride complexes with excess phosphine and dimethylamine was compared and contrasted with the same reaction involving preformed cationic a- ...