Synthesis and characterization of verdazyl radicals bearing pyridine or pyrimidine substituents: A new family of chelating spin-bearing ligands

CL Barr, PA Chase, RG Hicks, MT Lemaire…

Index: Barr, Christa L.; Chase, Preston A.; Hicks, Robin G.; Lemaire, Martin T.; Stevens, Cecilia L. Journal of Organic Chemistry, 1999 , vol. 64, # 24 p. 8893 - 8897

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Citation Number: 69

Abstract

The syntheses and characterization of two new 1, 5-dimethyl-6-oxoverdazyl radicals bearing 2-pyridine and 4, 6-dimethyl-2-pyrimidine rings as substituents are described. The radical precursors, the corresponding 1, 2, 4, 5-tetrazanes, were prepared by condensation of the bis (1-methylhydrazide) of carbonic acid with the appropriate aromatic aldehyde. Oxidation of 3-(4, 6-dimethyl-2-pyrimidyl)-1, 5-dimethyl-1, 2, 4, 5-tetrazane 6-oxide (7) with sodium ...