A practical and efficient green synthesis of β-aminophosphoryl compounds via the aza-Michael reaction in water

…, PV Petrovskii, ZS Klemenkova, NA Bondarenko…

Index: Matveeva, Ekaterina V.; Petrovskii, Pavel V.; Klemenkova, Zinaida S.; Bondarenko, Natalya A.; Odinets, Irina L. Comptes Rendus Chimie, 2010 , vol. 13, # 8-9 p. 964 - 970

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Citation Number: 13

Abstract

Biphasic systems room temperature imidazolium ionic liquid (RTIL)/water or water as a solvent significantly accelerate the addition of amines to vinylphosphoryl compounds hence opening green and effective synthesis of β-aminophosphoryl compounds in excellent yields over short reaction times. The application of water, being the cheapest and most non-toxic solvent, without any catalyst or co-solvent, is more advantageous as it provides a simple ...