Intramolecular olefinic aldehyde Prins reactions for the construction of five-membered rings

NH Andersen, SW Hadley, JD Kelly…

Index: Andersen, Niels H.; Hadley, Stephen W.; Kelly, James D.; Bacon, E. R. Journal of Organic Chemistry, 1985 , vol. 50, # 21 p. 4144 - 4151

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Citation Number: 46

Abstract

Four catalysts (Me2AlCl N SnC14> EtAIClz> EhAlCl) for the cyclization of olefinic aldehydes by an internal Prins mechanism have been compared by using systems that afford five- membered rings by type I and type I1 ene processes. Stannic chloride and MezAICl are ...