Contribution of GC??MS Analyses to the Determination of the Self??Ignition Mechanism of 1, 4??Dioxane in Chlorine

F Battin, M Dzierzynski, PM Marquaire…

Index: Battin, F.; Dzierzynski, M.; Marquaire, P. M.; Come, G. M.; Baronnet, F. Bulletin des Societes Chimiques Belges, 1990 , vol. 99, # 7 p. 483 - 489

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Citation Number: 3

Abstract

Abstract An experimental investigation in a conventional static apparatus of gas phase reactions between 1, 4 dioxane and chlorine has permitted to observe auto-ignitions above 100 C at subatmospheric pressure and to map out the limits of reaction zones in a pressure- temperature diagram. To achieve a better understanding of the reaction mechanism leading to these auto-ignitions, we have performed an experimental investigation of the slow ...