Experimental and Theoretical Approaches Toward Anion??Responsive Tripod–Lanthanide Complexes: Mixed??Donor Ligand Effects on Lanthanide Complexation and …

…, S Tsukamoto, H Tatewaki, S Shinoda…

Index: Kataoka, Yumiko; Paul, Dharam; Miyake, Hiroyuki; Yaita, Tsuyoshi; Miyoshi, Eisaku; Mori, Hirotoshi; Tsukamoto, Shinya; Tatewaki, Hiroshi; Shinoda, Satoshi; Tsukube, Hiroshi Chemistry - A European Journal, 2008 , vol. 14, # 17 p. 5258 - 5266

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Citation Number: 29

Abstract

Abstract A new series of tripods were designed to form anion-responsive, luminescent lanthanide complexes. These tripods contain pyridine, thiazole, pyrazine, or quinoline chromophores combined with amide carbonyl oxygen and tertiary nitrogen atoms. Crystallographic and EXAFS studies of the 10-coordinated tripod–La (NO 3) 3 complexes revealed that each La 3+ cation was cooperatively coordinated by one tetradentate tripod ...