Journal of fluorine chemistry

Preparation of perfluoroalkylthiohydroximates from perfluoroalkyl nitriles

WE Barnette

Index: Barnette,W.E. Journal of Fluorine Chemistry, 1984 , vol. 26, p. 161

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Citation Number: 1

Abstract

Abstract S-Methyl (Z)-2, 2, 2-trifluorothioacetohydroximate (1), S-methyl (Z)-2, 2, 3, 3, 3- pentafluorothiopropiohydroximate (2), and S-methyl (Z)-2, 2, 3, 3, 4, 4, 4- heptafluorothiobutyrohydroximate (3) were prepared by reaction of the corresponding perfluoroalkyl nitriles 4, 5, and 6 with methanethiol and hydroxylamine hydrochloride.