Synthesis

Synthesis of Conjugated Polyenes with Alkylanthryl and N-Alkylpyridinium Terminal Groups

F Effenberger, S Heid, R Merkle, P Zimmermann

Index: Effenberger; Heid; Merkle; Zimmermann Synthesis, 1995 , # 9 p. 1115 - 1120

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Citation Number: 7

Abstract

These two methylating agents were chosen to prove the influence of different electrochemically inert anions on the ability to form monolayers. Long-chain alkyl groups at the pyridine nitrogen could be introduced by reaction with trifluoromethanesulfonic acid esters 18 a, b. 21 According to known methods, 6'2" _22 we prepared the pyridinium salts 19a and b from 15b with 18 a, b in the presence of collidine in 42 and 71% yield, ...