Bis (cyclopentadienyl) titanium (III) chloride(Nugent s reagent)[1] is an efficient single- electron reductant and has been used as a versatile tool in organic synthesis,[2, 3] owing to the ease of handling, its functional-group compatibility, and a broad array of reactions that can be effected under relatively mild conditions. Today,[Cp2TiCl] is used as a catalyst for several types of radical reactions by employing a catalytic amount of [Cp2TiCl2] as a ...
