Advanced Synthesis & Catalysis

Ruthenium??Catalyzed Alkyne Oxidation with Part??Per??Million Catalyst Loadings

W Ren, J Liu, L Chen, X Wan

Index: Ren, Wei; Liu, Jinfeng; Chen, Long; Wan, Xiaobing Advanced Synthesis and Catalysis, 2010 , vol. 352, # 9 p. 1424 - 1428

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Citation Number: 46

Abstract

Abstract Using a catalytic system of the (cymene) ruthenium dichloride dimer,[Ru (cymene) Cl 2] 2,(0.001 mol%) and iodine (10 mol%), a variety of alkynes bearing different functional groups were oxidized with tert-butyl hydroperoxide (TBHP; 70% solution in water) under ...