Organofluorosilicates in Organic Synthesis. XVI. Synthesis of Organopentafluorosilicates via the Diels-Alder, Ene, and Friedel-Crafts Reaction. Their Transformations …

…, M Akita, Y Sugihara, T Iwahara, M Kumada

Index: Tamao, Kohei; Yoshida, Jun-ichi; Akita, Munetaka; Sugihara, Yoshihiro; Iwahara, Takahisa; Kumada, Makoto Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 1 p. 255 - 260

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Citation Number: 21

Abstract

Described herein are several representative examples of cleavage reactions of otherwise hardly accessible organopentafluorosilicates which are obtainable via the Diels-Alder reaction, ene reaction, and the Friedel-Crafts reaction of vinyl-, ethynyl-, or allyl- trichlorosilanes. The Diels-Alder reaction between vinyltrichlorosilane and o-xylylene generated in situ by debromination of α, α′-dibromo-o-xylene afforded (1, 2, 3, 4- ...