Interactions between Sulfur Ylides and Electrophilic Monosulfides

H Matsuyama, M Matsumoto, M Kobayashi…

Index: Matsuyama,H. et al. Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 1139 - 1142

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Citation Number: 4

Abstract

The catalytic activities of electrophilic monosulfides, Ar–S–R*(R*= CN, CF 3, OMe), for the transylidation reactions of sulfur ylide, Ph (Me)\ overset⊕ S–\ overset\ ominusC (CO 2 Me) 2, with alkyl sulfides and pyridines were investigated. Among these monosulfides, methyl arenesulfenates reacted with dimethylsulfonium phenacylide (or dimethylsulfonium ethoxycarbonylmethylide) to give α-(arylthio) phenacylides (or α-(arylthio) ...

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