Electronic Tuning of Iron–Oxo??Mediated C H Activation: Effect of Electron??Donating Ligand on Selectivity

Y Hitomi, K Arakawa, M Kodera

Index: Hitomi, Yutaka; Arakawa, Kengo; Kodera, Masahito Chemistry - A European Journal, 2013 , vol. 19, # 43 p. 14697 - 14701

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Citation Number: 14

Abstract

Abstract We have reported previously that an iron (III) complex supported by an anionic pentadentate monoamido ligand, dpaq H (dpaq H= 2-[bis (pyridin-2-ylmethyl)] amino-N- quinolin-8-yl-acetamido), promotes selective C [BOND] H hydroxylation with H 2 O 2 with high regioselectivity. Herein, we report on the preparation of Fe III–dpaq derivatives that have a series of substituent groups at the 5-position of a quinoline moiety in the parent ...