The Journal of Organic Chemistry

Reaction of thiolate, sulfite, and cyanide ions with cyclic aryl thiolsulfinates: dibenzo [ce]-1, 2-dithiin and naphtho [1, 8-cd]-1, 2-dithiole 1-oxides

B Boduszek, JL Kice

Index: Boduszek, Bogdan; Kice, John L. Journal of Organic Chemistry, 1982 , vol. 47, # 17 p. 3199 - 3207

Full Text: HTML

Citation Number: 13

Abstract

The behavior of cyclic thiolsulfiiates 5 and 6 (dibenzo [c, e]-l, 2-dithiin 1-oxide and naphtho [l, &cd]-l, 2-dithiole 1-oxide) upon treatment with either sulfite, cyanide, or t-Bus-ions has been examined and compared with the behavior of the corresponding thiolsulfonates 1 and 2 (dibemo [c, e]-1, 2-dithiin and naphtho [l, &cd]-l, 2-dithiole 1, l-dioxides). Very marked differences are observed. Whereas thiolsulfonates 1 and 2 are converted essentially ...