Journal of organometallic chemistry

Thermolyse von Arylhalogenboranen; Synthese von 1, 3-Dibora-und 1, 3-Borasilaindanen

W Schacht, D Kaufmann

Index: Schacht, Wolfgang; Kaufmann, Dieter Journal of Organometallic Chemistry, 1987 , vol. 331, # 2 p. 139 - 152

Full Text: HTML

Citation Number: 26

Abstract

Abstract The thermolysis of the 2-silylated or borylated arylboranes (3a-g, or 9a, b) has been investigated. The synthesis of the unknown starting boranes succeeds upon treatment of the (o-(dichloroboryl) phenyl) trimethylsilane (3b) with trimethylalane (giving 3e), tetramethylstannane (giving 3f) or diisopropylamine (giving 3g) and upon trimethylation of the 1, 2-bis (dichloroboryl) benzene (9a) with tetramethylstannane (giving 9b). In solution ...