Tetrahedron letters

Di-tert-butylmethylsilyl (DTBMS) trifluoromethanesulfonate. preparation and synthetic applications of DTBMS esters and enol ethers

…, BS Levison, RB Sharma, S Ghosh, RG Salomon

Index: Bhide, Rajeev S.; Levison, Bruce S.; Sharma, Ram B.; Ghosh, Subrata; Salomon, Robert G. Tetrahedron Letters, 1986 , vol. 27, # 6 p. 671 - 674

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Citation Number: 16

Abstract

Summary DTBMS triflate, readily available from dichloromethylsilane, provides carboxylic esters which resist reduction by hydridoaluminate or acid catalyzed hydrolysis, and vinylogous esters (enol ethers of hydroxymethylene ketones) which resist 1, 4-addition of methyllithium.