The Journal of Organic Chemistry

Reaction of ketene bis (trimethylsilyl) acetals with m-chloroperbenzoic acid. Synthesis of. alpha.-hydroxycarboxylic acids

GM Rubottom, R Marrero

Index: Rubottom,G.M.; Marrero,R. Journal of Organic Chemistry, 1975 , vol. 40, p. 3783 - 3784

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Citation Number: 48

Abstract

C Normalized. only 14% greater than that of benzonitrile, an indication of preponderance of addition over benzyl hydrogen abstraction for this toluene. p-Chlorotoluene is 50% more reactive than chlorobenzene, indicating that addition and benzyl hydrogen abstraction are roughly comparable in this case. p-Methoxytoluene is 270% more reactive than anisole, indicating that benzyl hydrogen abstraction is predominant for this toluene.

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