Kinetic and mechanistic studies of the reactions of cyclopentylperoxy and cyclohexylperoxy radicals with hydroperoxy radical

…, PD Lightfoot, B Noziere, TJ Wallington…

Index: Rowley, David M.; Lesclaux, Robert; Lightfoot, Phillip, D.; Noziere, Barbara; Wallington, Timothy J.; Hurley, Michael D. Journal of Physical Chemistry, 1992 , vol. 96, # 12 p. 4889 - 4894

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Citation Number: 57

Abstract

The kinetics and mechanism of the reactions c-C5H9O2+ H02-c-C5H900H+ 0 2 (1) and c- C6Hl102+ HO2-C-C6HlI00H+ O2 (2) have been studied using both the flash photolysis/UV absorption and continuous photolysa/FTIR product analysis techniques. End product analysis experiments at 295 f 2 K demonstrated that the yield of hydroperoxide was (96 f 3)% and (99 f 3)% for reactions 1 and 2, respectively, although systematic errors could ...