Novel diphenylphosphine derivatives of 2, 2′-bithiophene, 2, 2′: 5′, 2 ″-terthiophene, 2-(2′-thienyl) pyridine and 2, 6-di-2′-thienylpyridine. Crystal structures of …

…, RJ Haines, EI Lakoba, MH Sosabowski

Index: Field, John S.; Haines, Raymond J.; Lakoba, Elena I.; Sosabowski, M. Hal Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 24 p. 3352 - 3360

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Citation Number: 23

Abstract

Diphenylphosphine derivatives of various pyridines and polypyridines are of current interest, especially with respect to their use as ligands for the synthesis of transition metal complexes that function as catalysts. 1 We have synthesised a range of ligands of this type and, in particular, have reported the synthesis of 6-diphenylphosphino-2,2′-bipyridine and shown this to be a useful tridentate bridging ligand, in particular with regard to stabilising dinuclear ...