Reactions of Bis (chloromethyl) phosphinic (-Phosphinothioic) Chlorides with Silylated Carbamates and Trimethylsilyl N-Trimethylsilylacetimidoate

LK Kibardina, MA Pudovik, AN Pudovik

Index: Kibardina; Pudovik Russian Journal of General Chemistry, 2001 , vol. 71, # 3 p. 321 - 324

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Abstract

Abstract Bis (chloromethyl) phosphinic chloride reacts with trimethylsilyl methylcarbamate in benzene in the presence of a base to give trimethylsilyl bis (chloromethyl) phosphinate. The same reaction performed without a solvent and in the absence of a base yields trimethylsilyl bis (chloromethyl) phosphinate and bis (chloromethyl) phosphinic anhydride. Reaction of bis (chloromethyl) phosphinic chloride with trimethylsilyl diethylcarbamate yields N, N- ...