Journal of Organometallic Chemistry

Preparation of certain chloromethyl-and dichloromethyl-substituted chlorodisilanes and their behavior toward aluminum halides

K Tamao, M Kumada

Index: Tamao,K.; Kumada,M. Journal of Organometallic Chemistry, 1971 , vol. 30, p. 339 - 347

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Citation Number: 23

Abstract

Abstract Four new (chloromethyl) disilanes,(ClCH 2) Cl 2 SiSiCl 2 Me (I),(Cl 2 CH) Cl 2 SiSiCl 2 Me (II),(ClCH 2) MeClSiSiClMe 2 (III) and (ClCH 2) Me 2 SiSiCl 3 (IV), have been prepared and studied as to their attitude toward intramolecular rearrangement with aluminum chloride. The reactivity decreases in the order:(III)>(IV)>(II)⪢(I). Similar reactivity to rearrangement of Me 3 SiSiMe 2 (CH 2 Br)(V), ClMe 2 SiSiMe 2 (CH 2 Br)(VI) and Me 3 ...