Tetrahedron letters

2-Trimethylsilylvinylboranes: highly reactive and selective diels-alder equivalents of 2-trimethylsilylvinyl alcohol and acetylene

DA Singleton, JP Martinez

Index: Singleton, Daniel A.; Martinez, Jose P. Tetrahedron Letters, 1991 , vol. 32, # 50 p. 7365 - 7368

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Citation Number: 46

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The readily available 2-trimethylsilylvinyl-9-BBN (1) is a highly reactive and selective dienophile. The Diels-Alder products are easily converted into trimethylsilylcyclohexenols and 1,4-cyclohexadienes. ... J. Org. Chem., 56 (1991), p. 1888 and references therein.