Transetherification of organosilicon amines with cellosolve and trimethylsilanol

…, AV Nikitin, VM Kopylov, IB Sokol'skaya

Index: Kovyazin; Nikitin; Kopylov; Sokol'skaya Russian Journal of General Chemistry, 2003 , vol. 73, # 9 p. 1383 - 1387

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Abstract

Abstract Kinetics of transetherification of (3-aminopropyl) trimethoxysilane,[3-N-(2- aminoethyl) aminopropyl] trimethoxysilane, and (3-aminopropyl) triethoxysilana with Cellosolve and trimethylsilanol were studied. The example of [3-N-(2-aminoethyl) aminopropyl] trimethoxysilane was used to show that the activation energies of the direct and reverse reactions are equal to each other both in the first and in the second stages, ...