Hydrophosphination of alkoxyalkenes catalyzed by transition metal complexes

…, IG Trostyanskaya, MA Kazankova…

Index: Shulyupin; Trostyanskaya; Kazankova; Beletskaya Russian Journal of Organic Chemistry, 2006 , vol. 42, # 1 p. 17 - 22

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Citation Number: 14

Abstract

Abstract Diphenylphosphine adds to alkyl vinyl ethers in the presence of Ni (II) and Pd (II) complexes with a high regioselectivity, leading to exclusive formation of the corresponding Markownikoff adducts which were isolated as 1-alkoxyalkyl (diphenyl) phosphine oxides via oxidation with hydrogen peroxide.

110-87-2

3,4-Dihydro-2H-pyran

~39%

Wittig and horner-wittig coupling reactions of 2-substituted...

[Ley, Steven V.; Lygo, Barry; Organ, Helen M.; Wonnacott, Anne Tetrahedron, 1985 , vol. 41, # 18 p. 3825 - 3836]

Catalytic Hydrophosphination of alkenylalkyl ethers

[Kazankova, Marina A.; Shulyupin, Mstislav O.; Beletskaya, Irina P. Synlett, 2003 , # 14 p. 2155 - 2158]

Wittig and horner-wittig coupling reactions of 2-substituted...

[Ley, Steven V.; Lygo, Barry; Organ, Helen M.; Wonnacott, Anne Tetrahedron, 1985 , vol. 41, # 18 p. 3825 - 3836]