N-Benzyl-N-phosphino-tert-butylsulfinamide and Its Coordination Modes with Ir (I), Cu (I), Pd (II), and Pt (II): P, S or P, O?

…, EC Escudero-Adán, A Riera, X Verdaguer

Index: Brun, Sandra; Parera, Magda; Pla-Quintana, Anna; Roglans, Anna; Leon, Thierry; Achard, Thierry; Sol, Jordi; Verdaguer, Xavier; Riera, Antoni Tetrahedron, 2010 , vol. 66, # 46 p. 9032 - 9040

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Citation Number: 7

Abstract

Here we studied the coordination mode of optically pure N-benzyl-N-phosphino-tert- butylsulfinamide (1a) toward Ir (I), Cu (I), Pd (II), and Pt (II). Ligand 1a can work as a hemilabile bidentate P, O or P, S or monodentate P ligand depending on the nature of the