Reactions of 7-bromonorcarane with nucleophiles by the SRN1 mechanism. Novel nucleophilic substitutions on the cyclopropane ring

…, AN Santiago, SM Palacios

Index: Rossi, Roberto A.; Santiago, Ana N.; Palacios, Sara M. Journal of Organic Chemistry, 1984 , vol. 49, # 18 p. 3387 - 3388

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Citation Number: 20

Abstract

The mechanism of radical nucleophilic substitution, or Sml, is a chain process that has radical and radical anions as intermediates.'The main steps of the propagation cycle of this mechanism are fragmentation of the radical anion of the substrate (eq l), coupling of the radical with the nucleophile (eq 2), and electron transfer from the radical anion of the substitution product to the substrate (eq 3), the step which completes the chain ...