e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Neighboring group participation in organic redox reactions. 8. Kinetics and products of the aqueous iodine oxidation of 3-hydroxy-and 3-methoxy-1, 5- …
…, RM Kessler, DL DeLeeuw, MM Olmstead…
Index: Doi, Joyce Takahashi; Kessler, Richard M.; deLeeuw, David L.; Olmstead, Marilyn M.; Musker, W. Kenneth Journal of Organic Chemistry, 1983 , vol. 48, # 21 p. 3707 - 3712
These rate constants are similar to those for the reaction of tert-butoxyl with dimethylamine where the rate con- stant for NH abstraction is 1.1 X lo7 Ml sl while that for CH abstraction is 6.6 X lo7 M-' Optical signals due to phenylthiyl radicals generated from diphenyldisulfide were not quenched by addition of thiophene, furan, or pyrrole, indicating that the addition of this radical must be relatively slow (
