Phytochemistry

13 C NMR spectral assignment of the A-ring of polyoxygenated flavones

…, K Shibata, K Yamashita, M Tsukayama, Y Kawamura

Index: Horie, Tokunaru; Ohtsuru, Yoshizumi; Shibata, Kenichi; Yamashita, Kazuyo; Tsukayama, Masao; Kawamura, Yasuhiko Phytochemistry, 1998 , vol. 47, # 5 p. 865 - 874

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Citation Number: 111

Abstract

The 13C NMR spectra of polyhydroxyflavones were systematically examined by using about 70 examples which have a 4-methoxyphenyl B-ring, such as 5, 6, 7-, 5, 7, 8 and 5, 6, 8- trioxygenated and 5, 6, 7, 8-tetraoxygenated flavones and flavonols, and the following results were obtained. In the 13C NMR spectra of flavones, the signals at the 2-, 3-and 4- positions in the C-ring were hardly affected by the substituents on the A-ring except for ...