The Journal of Organic Chemistry

Small-ring compounds. XV. The dehydration of trans-. alpha.,. alpha.,. alpha.',. alpha.'-tetramethyl-1, 2-cyclopropanedimethanol

T Shono, T Yoshimura, R Oda

Index: Shono,T. et al. Journal of Organic Chemistry, 1967 , vol. 32, p. 1088 - 1091

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Citation Number: 5

Abstract

The dehydration of trans-cr,~, cr',~'-tetramethyl-l, 2-cyclopropanedimethanol (I), catalyzed by p-toluenesulfonic acid yielded six products: two cyclic ethers (4 and 7), three unsaturated hydroxy compounds (2, 5, and 8), and one unsaturated ketone (9). The react, ion routes were discussed on the basis of the structures of the products and the result, s of the gas chromatographic analysis.