Journal of organometallic chemistry

Siliciumverbindungen mit starken intramolekularen sterischen wechselwirkungen: XVIII. Oxa-, thia-und selena-trisiletane durch ringerweiterungsreaktionen

M Weidenbruch, A Schäfer

Index: Weidenbruch, Manfred; Schaefer, Annemarie Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. 231 - 234

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Abstract

Abstract The reaction of hexa-t-butylcyclotrisilane with sulfur or selenium gives the corresponding thia-and selena-trisiletanes. Oxidation of the same cyclotrisilane by oxygen, dimethylsulfoxide, or m-chloroperbenzoic acid leads to three oxidation products which possess one, two, or three oxygen atoms, respectively in the ring system.