… of [Fe (η 5-C 5 Me 5)(η 5-C 3 t Bu 3 P 2)] and of the adducts [Fe (η 5-C 5 Me 5)(η 5-C 2 t Bu 2 P 3) Mo (CO) 5] and [Fe (η 5-C 5 Me 5 (η 5-C 2 t Bu 2 P 3) W (CO) 5] 1

…, R Bartsch, A Fischer, PG Jones, R Schmutzler

Index: Mueller, Christian; Bartsch, Rainer; Fischer, Axel; Jones, Peter G.; Schmutzler, Reinhard Journal of Organometallic Chemistry, 1996 , vol. 512, # 1-2 p. 141 - 148

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Abstract

Synthesis and structural studies of the iron “sandwich” complex [Fe (η5-C5Me5 (η- C3tBu3P2)] 1 are described. The lone pair electrons of the two adjacent phosphorus atoms of the C2tBu2P3 ring in the triphospha-ferrocene complex [Fe (η5-C5Me5)(η5-C2tBu2P3)] 2 can ligate to other metal centres. The results of single crystal X-ray structural studies of the molybdenum and tungsten pentacarbonyl η1-complexes [Fe (η5-C5Me5)(η5-C2tBu2P3) ...