Synthetic communications

Regioselective iodination of activated arenes using phenyl trimethylammonium dichloroiodate in ionic liquid under microwave irradiation

RD Tilve, VR Kanetkar

Index: Tilve, Rutuja D.; Kanetkar, Vinod R. Synthetic Communications, 2005 , vol. 35, # 10 p. 1313 - 1318

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Citation Number: 10

Abstract

View all references we report herein the use of ionic liquids and ionic liquids in conjunction with microwave heating as promoters and a recyclable system for the synthesis of iodoarenes using phenyl trimethyl ammonium dichloroiodate (PTMA ICl 2 ) (Scheme 1). Phenyl trimethyl ammonium chloride was prepared as follows: To the black solution of ICl (0.1 mol) in dichloromethane (MDC) (200 ml) was added dropwise a solution of phenyltrimethylammonium chloride ...