Synthesis of olefins from nitroesters

…, GA Karpov, IS Mikhailova, EV Aleksandrova…

Index: Kochergin; Blinova; Karpov; Mikhailova; Aleksandrova; Korol Pharmaceutical Chemistry Journal, 1999 , vol. 33, # 1 p. 41 - 44

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Citation Number: 3

Abstract

The reaction of 13-H-elimination in organic nitrates, involving detachment of the nitric acid molecule with the formation of unsaturated compounds [2-4], is still insufficiently studied from the standpoint of preparative chemistry. There are only a few papers describing the synthesis of 2-nitrosoolefins [5-7], fumaric acid [8], 2-nitroolefins (polymerized in the course of the reaction)[9], unsaturated steroidal nitro compounds [! 0], and nitro (dinitro)- ...