Dalton Transactions

Synthesis of trifunctional ligands containing thiophosphoryl, pyridine and pyridine N-oxide donor groups

X Gan, EN Duesler, S Parveen, RT Paine

Index: Gan, Xin-Min; Duesler, Eileen N.; Parveen, Sahrah; Paine, Robert T. Dalton Transactions, 2003 , # 24 p. 4704 - 4708

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Citation Number: 6

Abstract

The trifunctional mixed donor ligands 2, 6-[R2P (S) CH2] 2C5H3N 1 (R= Ph 1a, Tol 1b, n-Bu, 1c) and 2, 6-[R2P (S) CH2] 2C5H3NO 2 (R= Ph 2a, Tol 2b, n-Bu, 2c) have been prepared and characterized by spectroscopic (MS, IR, NMR) techniques. The coordination chemistry of one derivative 1a has been examined and the complex {[Ph2P (S) CH2] 2C5H3N} Ni (NO3) 2 has been crystallized and characterized by single-crystal X-ray diffraction ...