Chemistry Letters

Stannous (II) triflate promoted rearrangement of β-keto sulfoxides. Synthesis of 1, 4-diketones

M Shimizu, T Akiyama, T Mukaiyama

Index: Shimizu, Makoto; Akiyama, Takahiko; Mukaiyama, Teruaki Chemistry Letters, 1984 , p. 1531 - 1534

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Citation Number: 13

Abstract

CHEMISTRY LETTERS, pp. 1531 - 1534, 1984. © The Chemical Society of Japan 1984 STANNOUS (II) TRIFLATE PROMOTED REARRANGEMENT OF ß-KETO SULFOXIDES. SYNTHESIS OF 1,4-DIKETONES Makoto SHIMIZU, Takahiko AKIYAMA, and Teruaki MUKAIYAMA Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113 Stannous triflate promotes rearrangement of ß-keto sulfoxides to generate a-thiocarbocation, which ...