Tetrahedron letters

Chloroalkyl 1, 2-dioxolanes from unsaturated hydroperoxides and t-butyl hypochlorite.

AJ Bloodworth, NA Tallant

Index: Bloodworth; Tallant Tetrahedron Letters, 1990 , vol. 31, # 48 p. 7077 - 7080

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Citation Number: 8

Abstract

Abstract Five monocyclic and one bicyclic 3-(1-chloroalkyl)-1, 2-dioxolanes have been prepared by reaction of alk-3-en-1-yl hydroperoxides with t-butyl hypochlorite in CH 2 Cl 2 in the presence of pyridine or silica; cyclooct-4-en-1-yl hydroperoxide with BuOCl/SiO 2