Kinetics of ozonation. 1. Electron-deficient alkenes

WA Pryor, D Giamalva, DF Church

Index: Pryor, William A.; Giamalva, David; Church, Daniel F. Journal of the American Chemical Society, 1983 , vol. 105, # 23 p. 6858 - 6861

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Citation Number: 60

Abstract

Conclusions The published experimental value for AHfo (g) of diphenylcyclopropenone is too high by as much as 50 kcal/mol corresponding to a 2.5% error in the heat of combustion, possibly due to the presence of a small amount of impurity in the compound tested in the earlier work. More refined calorimetric measure-