Synlett

Oxidation of diphenyl diselenide with 2, 3-dichloro-5, 6-dicyanobenzoquinone (DDQ). A new method for the electrophilic phenylselenenylation of alkenes under mild …

…, L Testaferri, A Temperini, L Bagnoli, F Marini, C Santi

Index: Tiecco; Testaferri; Temperini; Bagnoli; Marini; Santi Synlett, 2001 , # 11 p. 1767 - 1771

Full Text: HTML

Citation Number: 4

Abstract

Abstract: The oxidation of diphenyl diselenide with 2, 3-dichloro-5, 6-dicyanobenzoquinone (DDQ) represents a convenient mild method to produce a strongly electrophilic phenylselenium reagent. Clean phenylseleno methoxylations and hydroxylations of alkenes containing different types of functional groups can be effected by working in methanol or in acetonitrile and water, respectively. This new electrophilic reagent can also be employed ...

~55%

Detail

~7%

Detail

Cyclofunctionalisation of unsaturated acids with benzenesele...

[Clive, Derrick L. J.; Russel, Charles G.; Chittattu, Gim; Singh, Alok Tetrahedron, 1980 , vol. 36, p. 1399 - 1408]

N-Phenylselenosaccharin (NPSSac): a new electrophilic seleni...

[Tingoli, Marco; Diana, Rosita; Panunzi, Barbara Tetrahedron Letters, 2006 , vol. 47, # 43 p. 7529 - 7531]

Phenylseleno-lactonization of olefinic nitriles promoted byp...

[Tiecco, Marcello; Testaferri, Lorenzo; Tingoli, Marco; Bartoli, Donatella Tetrahedron, 1989 , vol. 45, # 21 p. 6819 - 6832]

Enantioselective Henry addition of methyl 4-nitrobutyrate to...

[Kanizsai, Ivan; Szakonyi, Zsolt; Sillanpaeae, Reijo; D'hooghe, Matthias; Kimpe, Norbert De; Fueloep, Ferenc Tetrahedron Asymmetry, 2006 , vol. 17, # 20 p. 2857 - 2863]

Enzymatic resolution of 5??phenylselanyltetrahydro??2??furan...

[Clososki, Giuliano C.; Costa, Carlos E.; Missio, Lauri J.; Cass, Quezia B.; Comasseto, Joao V. Synthetic Communications, 2004 , vol. 34, # 5 p. 817 - 828]